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Cobalt-Catalyzed Methoxycarbonylation of Substituted Dichlorobenzenes as an Example of a Facile Radical Anion Nucleophilic Substitution in Chloroarenes

A thorough mechanistic study on cobalt-catalysed direct methoxycarbonylation reactions of chlorobenzenes in the presence of methyl oxirane on a wide range of substrates, including poly- and monochloro derivatives with multiple substituents, is reported. The results demonstrate that the reaction is p...

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Detalles Bibliográficos
Autores principales: Khaibulova, Tatyana S., Boyarskaya, Irina A., Larionov, Evgeny, Boyarskiy, Vadim P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6270984/
https://www.ncbi.nlm.nih.gov/pubmed/24806583
http://dx.doi.org/10.3390/molecules19055876