Pauson-Khand Reaction of Internal Dissymmetric Trifluoromethyl Alkynes. Influence of the Alkene on the Regioselectivity

The scope of the Pauson-Khand reaction (PKR) of internal trifluoromethyl alkynes, previously described with norbornadiene, is expanded to norbornene and ethylene. A thorough structural analysis of the resulting PK adducts has been carried out to unveil that α-trifluoromethylcyclopentenones are prefe...

Descripción completa

Detalles Bibliográficos
Autores principales: Aiguabella, Nuria, Arce, Elsa M., del Pozo, Carlos, Verdaguer, Xavier, Riera, Antoni
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2014
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6271263/
https://www.ncbi.nlm.nih.gov/pubmed/24496269
http://dx.doi.org/10.3390/molecules19021763

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6271263/
https://www.ncbi.nlm.nih.gov/pubmed/24496269
http://dx.doi.org/10.3390/molecules19021763

Ejemplares similares