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Synthesis, Characterisation and Reactions of Phosphine-Substituted Alkynylboronates and Alkynyltrifluoroborate Salts

The synthesis and structural characterisation of phosphine-substituted alkynylboronates is reported. A P(III)-centred alkynylboronate (2) was prepared that showed little evidence for the conjugation of the P-lone pair to the boron via the alkyne π-system, as judged by X-ray crystallography studies o...

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Detalles Bibliográficos
Autores principales: Vivat, Jérôme F., Bachollet, Sylvestre P. J. T., Adams, Harry, Harrity, Joseph P. A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6271442/
https://www.ncbi.nlm.nih.gov/pubmed/25529019
http://dx.doi.org/10.3390/molecules191221324