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Chlorine Isotope Effects from Isotope Ratio Mass Spectrometry Suggest Intramolecular C-Cl Bond Competition in Trichloroethene (TCE) Reductive Dehalogenation

Chlorinated ethenes are prevalent groundwater contaminants. To better constrain (bio)chemical reaction mechanisms of reductive dechlorination, the position-specificity of reductive trichloroethene (TCE) dehalogenation was investigated. Selective biotransformation reactions (i) of tetrachloroethene (...

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Detalles Bibliográficos
Autores principales: Cretnik, Stefan, Bernstein, Anat, Shouakar-Stash, Orfan, Löffler, Frank, Elsner, Martin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6271514/
https://www.ncbi.nlm.nih.gov/pubmed/24853618
http://dx.doi.org/10.3390/molecules19056450