The Dynamical Behavior of the s-Trioxane Radical Cation—A Low-Temperature EPR and Theoretical Study

The radical cation of s-trioxane, radiolytically generated in a freon (CF(3)CCl(3)) matrix, was studied in the 10–140 K temperature region. Reversible changes of the EPR spectra were observed, arising from both ring puckering and ring inversion through the molecular plane. The ESREXN program based o...

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Detalles Bibliográficos
Autores principales: Naumov, Sergej S., Knolle, Wolfgang, Naumov, Sergej P., Pöppl, Andreas, Janovský, Igor
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2014
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6271718/
https://www.ncbi.nlm.nih.gov/pubmed/25353382
http://dx.doi.org/10.3390/molecules191117305

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6271718/
https://www.ncbi.nlm.nih.gov/pubmed/25353382
http://dx.doi.org/10.3390/molecules191117305

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