Photochemistry of Benzotriazoles: Generation of 1,3-Diradicals and Intermolecular Cycloaddition as a New Route toward Indoles and Dihydropyrrolo[3,4-b]Indoles

Irradiation of benzotriazoles 1a–e at λ = 254 nm in acetonitrile solution generated the corresponding 1,3-diradicals which underwent intermolecular cycloaddition with maleimides to afford the corresponding dihydropyrrolo[3,4-b]indoles and with acetylene derivatives to afford indoles as the major pro...

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Detalles Bibliográficos
Autores principales: Al-Jalal, Nader A., Ibrahim, Maher R., Al-Awadi, Nouria A., Elnagdi, Mohamed H., Ibrahim, Yehia A.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2014
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6271786/
https://www.ncbi.nlm.nih.gov/pubmed/25514217
http://dx.doi.org/10.3390/molecules191220695

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6271786/
https://www.ncbi.nlm.nih.gov/pubmed/25514217
http://dx.doi.org/10.3390/molecules191220695

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