Dissociative Electron Transfer to Diphenyl-Substituted Bicyclic Endoperoxides: The Effect of Molecular Structure on the Reactivity of Distonic Radical Anions and Determination of Thermochemical Parameters

The heterogeneous electron transfer reduction of the bicyclic endoperoxide 1,4-diphenyl-2,3-dioxabicyclo[2.2.1]hept-5-ene (4) was investigated in N,N-dimethylformamide at a glassy carbon electrode. The endoperoxide reacts by a concerted dissociative ET mechanism resulting in reduction of the O-O bon...

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Detalles Bibliográficos
Autores principales: Magri, David C., Workentin, Mark S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2014
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6271848/
https://www.ncbi.nlm.nih.gov/pubmed/25116807
http://dx.doi.org/10.3390/molecules190811999

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6271848/
https://www.ncbi.nlm.nih.gov/pubmed/25116807
http://dx.doi.org/10.3390/molecules190811999

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