Ni-Catalyzed Homoallylation of Polyhydroxy N,O-Acetals with Conjugated Dienes Promoted by Triethylborane

In the presence of Ni-catalyst and triethylborane, N,O-acetals prepared from glycolaldehyde and glyceraldehyde with primary amines in situ underwent homoallylation with conjugated dienes to provide 2-amino-5-hexenols in high regio- and stereoselectivity. Under similar reaction conditions, N,O-acetal...

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Detalles Bibliográficos
Autores principales: Mori, Takamichi, Akioka, Yusuke, Onodera, Gen, Kimura, Masanari
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2014
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6271873/
https://www.ncbi.nlm.nih.gov/pubmed/24991760
http://dx.doi.org/10.3390/molecules19079288

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6271873/
https://www.ncbi.nlm.nih.gov/pubmed/24991760
http://dx.doi.org/10.3390/molecules19079288

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