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Exploiting Natural Products to Build Metalla-Assemblies: The Anticancer Activity of Embelin-Derived Rh(III) and Ir(III) Metalla-Rectangles
Six new pentamethylcyclopentadienyl Rh(III) and Ir(III) metalla-rectangles ([3](CF(3)SO(3))(4)–[8](CF(3)SO(3))(4)) have been prepared by a self-assembly strategy using the embelin-derived metalla-clips (η(5)-C(5)Me(5))(2)M(2)(μ(4)-C(6)HRO(4)-κO)Cl(2) (M = Rh, 1; M = Ir, 2; R = (CH(2))(10)CH(3)) and...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6271910/ https://www.ncbi.nlm.nih.gov/pubmed/24824137 http://dx.doi.org/10.3390/molecules19056031 |