Improved Metathesis Lifetime: Chelating Pyridinyl-Alcoholato Ligands in the Second Generation Grubbs Precatalyst

Hemilabile ligands can release a free coordination site “on demand” of an incoming nucleophilic substrate while occupying it otherwise. This is believed to increase the thermal stability and activity of catalytic systems and therefore prevent decomposition via free coordination sites. In this invest...

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Detalles Bibliográficos
Autores principales: du Toit, Jean I., Jordaan, Margaritha, Huijsmans, Carlijn A. A., Jordaan, Johannes H. L., van Sittert, Cornelia G. C. E., Vosloo, Hermanus C. M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2014
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272008/
https://www.ncbi.nlm.nih.gov/pubmed/24786690
http://dx.doi.org/10.3390/molecules19055522

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272008/
https://www.ncbi.nlm.nih.gov/pubmed/24786690
http://dx.doi.org/10.3390/molecules19055522

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