σ- versus π-Activation of Alkynyl Benzoates Using B(C(6)F(5))(3)

We have prepared a range of alkynyl benzoates in high yields and have investigated their reactivities with the strong Lewis acid B(C(6)F(5))(3). In such molecules both σ-activation of the carbonyl and π-activation of the alkyne are possible. In contrast to the reactivity of propargyl esters with B(C...

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Detalles Bibliográficos
Autores principales: Bähr, Alexander, Wilkins, Lewis C., Ollegott, Kevin, Kariuki, Benson M., Melen, Rebecca L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2015
Materias:
Communication
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272168/
https://www.ncbi.nlm.nih.gov/pubmed/25774488
http://dx.doi.org/10.3390/molecules20034530

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272168/
https://www.ncbi.nlm.nih.gov/pubmed/25774488
http://dx.doi.org/10.3390/molecules20034530

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