Acid Catalyzed Alcoholysis of Sulfinamides: Unusual Stereochemistry, Kinetics and a Question of Mechanism Involving Sulfurane Intermediates and Their Pseudorotation

The synthesis of optically active sulfinic acid esters has been accomplished by the acid catalyzed alcoholysis of optically active sulfinamides. Sulfinates are formed in this reaction with a full or predominant inversion of configuration at chiral sulfur or with predominant retention of configuratio...

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Detalles Bibliográficos
Autores principales: Bujnicki, Bogdan, Drabowicz, Józef, Mikołajczyk, Marian
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2015
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272183/
https://www.ncbi.nlm.nih.gov/pubmed/25679053
http://dx.doi.org/10.3390/molecules20022949

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272183/
https://www.ncbi.nlm.nih.gov/pubmed/25679053
http://dx.doi.org/10.3390/molecules20022949

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