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Cu (II)-Catalyzed Asymmetric Henry Reaction with a Novel C(1)-Symmetric Aminopinane-Derived Ligand
A novel C(1)-symmetric dinitrogen ligand was synthesized in high yield from commercially available (1R,2R,3R,5S)-(−)-isopinocampheylamine and 1-methyl-2-imidazolecarboxaldehyde. In combination with Cu(OAc)(2)∙H(2)O, this new ligand promote the reaction between nitromethane and aliphatic aldehydes wi...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2015
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272271/ https://www.ncbi.nlm.nih.gov/pubmed/25859780 http://dx.doi.org/10.3390/molecules20046224 |