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Cu (II)-Catalyzed Asymmetric Henry Reaction with a Novel C(1)-Symmetric Aminopinane-Derived Ligand

A novel C(1)-symmetric dinitrogen ligand was synthesized in high yield from commercially available (1R,2R,3R,5S)-(−)-isopinocampheylamine and 1-methyl-2-imidazolecarboxaldehyde. In combination with Cu(OAc)(2)∙H(2)O, this new ligand promote the reaction between nitromethane and aliphatic aldehydes wi...

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Detalles Bibliográficos
Autores principales: Filippova, Liudmila, Stenstrøm, Yngve, Hansen, Trond Vidar
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2015
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272271/
https://www.ncbi.nlm.nih.gov/pubmed/25859780
http://dx.doi.org/10.3390/molecules20046224