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Properties of Manganese(III) Ferrocenyl-β-Diketonato Complexes Revealed by Charge Transfer and Multiplet Splitting in the Mn 2p and Fe 2p X-Ray Photoelectron Envelopes

A series of ferrocenyl-functionalized β-diketonato manganese(III) complexes, [Mn(FcCOCHCOR)(3)] with R = CF(3), CH(3), Ph (phenyl) and Fc (ferrocenyl) was subjected to a systematic XPS study of the Mn 2p(3/2) and Fe 2p(3/2) core-level photoelectron lines and their satellite structures. A charge-tran...

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Detalles Bibliográficos
Autores principales: Buitendach, Blenerhassitt E., Erasmus, Elizabeth, Niemantsverdriet, J. W. (Hans), Swarts, Jannie C.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6272950/
https://www.ncbi.nlm.nih.gov/pubmed/27792197
http://dx.doi.org/10.3390/molecules21111427