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Unimolecular Solvolyses in Ionic Liquid: Alcohol Dual Solvent Systems
A study was undertaken of the solvolysis of pivaloyl triflate in a variety of ionic liquid:alcohol solvent mixtures. The solvolysis is a k(Δ) process (i.e., a process in which ionization occurs with rearrangement), and the resulting rearranged carbocation intermediate reacts with the alcohol cosolve...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273061/ https://www.ncbi.nlm.nih.gov/pubmed/26751434 http://dx.doi.org/10.3390/molecules21010060 |