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Isolation of a Cyclic (Alkyl)(amino)germylene
A 1,4-addition of a dichlorogermylene dioxane complex with α,β-unsaturated imine 1 gave a dichlorogermane derivative 2 bearing a GeC(3)N five-membered ring skeleton. By reducing 2 with KC(8), cyclic (alkyl)(amino)germylene 3 was synthesized and fully characterized. Germylene 3 readily reacted with T...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273211/ https://www.ncbi.nlm.nih.gov/pubmed/27483223 http://dx.doi.org/10.3390/molecules21080990 |