Isolation of a Cyclic (Alkyl)(amino)germylene

A 1,4-addition of a dichlorogermylene dioxane complex with α,β-unsaturated imine 1 gave a dichlorogermane derivative 2 bearing a GeC(3)N five-membered ring skeleton. By reducing 2 with KC(8), cyclic (alkyl)(amino)germylene 3 was synthesized and fully characterized. Germylene 3 readily reacted with T...

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Autores principales: Wang, Liliang, Lim, Yi Shan, Li, Yongxin, Ganguly, Rakesh, Kinjo, Rei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
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Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273211/
https://www.ncbi.nlm.nih.gov/pubmed/27483223
http://dx.doi.org/10.3390/molecules21080990
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author Wang, Liliang
Lim, Yi Shan
Li, Yongxin
Ganguly, Rakesh
Kinjo, Rei
author_facet Wang, Liliang
Lim, Yi Shan
Li, Yongxin
Ganguly, Rakesh
Kinjo, Rei
author_sort Wang, Liliang
collection PubMed
description A 1,4-addition of a dichlorogermylene dioxane complex with α,β-unsaturated imine 1 gave a dichlorogermane derivative 2 bearing a GeC(3)N five-membered ring skeleton. By reducing 2 with KC(8), cyclic (alkyl)(amino)germylene 3 was synthesized and fully characterized. Germylene 3 readily reacted with TEMPO, N(2)O and S(8), producing the 1:2 adduct 4, the oxo-bridged dimer 5 and the sulfido-bridged dimer 6, respectively.
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spelling pubmed-62732112018-12-28 Isolation of a Cyclic (Alkyl)(amino)germylene Wang, Liliang Lim, Yi Shan Li, Yongxin Ganguly, Rakesh Kinjo, Rei Molecules Article A 1,4-addition of a dichlorogermylene dioxane complex with α,β-unsaturated imine 1 gave a dichlorogermane derivative 2 bearing a GeC(3)N five-membered ring skeleton. By reducing 2 with KC(8), cyclic (alkyl)(amino)germylene 3 was synthesized and fully characterized. Germylene 3 readily reacted with TEMPO, N(2)O and S(8), producing the 1:2 adduct 4, the oxo-bridged dimer 5 and the sulfido-bridged dimer 6, respectively. MDPI 2016-07-29 /pmc/articles/PMC6273211/ /pubmed/27483223 http://dx.doi.org/10.3390/molecules21080990 Text en © 2016 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC-BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Wang, Liliang
Lim, Yi Shan
Li, Yongxin
Ganguly, Rakesh
Kinjo, Rei
Isolation of a Cyclic (Alkyl)(amino)germylene
title Isolation of a Cyclic (Alkyl)(amino)germylene
title_full Isolation of a Cyclic (Alkyl)(amino)germylene
title_fullStr Isolation of a Cyclic (Alkyl)(amino)germylene
title_full_unstemmed Isolation of a Cyclic (Alkyl)(amino)germylene
title_short Isolation of a Cyclic (Alkyl)(amino)germylene
title_sort isolation of a cyclic (alkyl)(amino)germylene
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273211/
https://www.ncbi.nlm.nih.gov/pubmed/27483223
http://dx.doi.org/10.3390/molecules21080990
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AT limyishan isolationofacyclicalkylaminogermylene
AT liyongxin isolationofacyclicalkylaminogermylene
AT gangulyrakesh isolationofacyclicalkylaminogermylene
AT kinjorei isolationofacyclicalkylaminogermylene

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