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Isolation of a Cyclic (Alkyl)(amino)germylene

A 1,4-addition of a dichlorogermylene dioxane complex with α,β-unsaturated imine 1 gave a dichlorogermane derivative 2 bearing a GeC(3)N five-membered ring skeleton. By reducing 2 with KC(8), cyclic (alkyl)(amino)germylene 3 was synthesized and fully characterized. Germylene 3 readily reacted with T...

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Detalles Bibliográficos
Autores principales: Wang, Liliang, Lim, Yi Shan, Li, Yongxin, Ganguly, Rakesh, Kinjo, Rei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273211/
https://www.ncbi.nlm.nih.gov/pubmed/27483223
http://dx.doi.org/10.3390/molecules21080990

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