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Reactions of an Isolable Dialkylsilylene with Aroyl Chlorides. A New Route to Aroylsilanes

The reactions of isolable dialkylsilylene 1 with aromatic acyl chlorides afforded aroylsilanes 3a–3c exclusively. Aroylsilanes 3a–3c were characterized by (1)H-, (13)C-, and (29)Si-NMR spectroscopy, high-resolution mass spectrometry (HRMS), and single-crystal molecular structure analysis. The reacti...

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Detalles Bibliográficos
Autores principales: Xiao, Xu-Qiong, Liu, Xupeng, Lu, Qiong, Li, Zhifang, Lai, Guoqiao, Kira, Mitsuo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273370/
https://www.ncbi.nlm.nih.gov/pubmed/27754460
http://dx.doi.org/10.3390/molecules21101376