Reactions of an Isolable Dialkylsilylene with Aroyl Chlorides. A New Route to Aroylsilanes

The reactions of isolable dialkylsilylene 1 with aromatic acyl chlorides afforded aroylsilanes 3a–3c exclusively. Aroylsilanes 3a–3c were characterized by (1)H-, (13)C-, and (29)Si-NMR spectroscopy, high-resolution mass spectrometry (HRMS), and single-crystal molecular structure analysis. The reacti...

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Detalles Bibliográficos
Autores principales: Xiao, Xu-Qiong, Liu, Xupeng, Lu, Qiong, Li, Zhifang, Lai, Guoqiao, Kira, Mitsuo
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273370/
https://www.ncbi.nlm.nih.gov/pubmed/27754460
http://dx.doi.org/10.3390/molecules21101376
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author Xiao, Xu-Qiong
Liu, Xupeng
Lu, Qiong
Li, Zhifang
Lai, Guoqiao
Kira, Mitsuo
author_facet Xiao, Xu-Qiong
Liu, Xupeng
Lu, Qiong
Li, Zhifang
Lai, Guoqiao
Kira, Mitsuo
author_sort Xiao, Xu-Qiong
collection PubMed
description The reactions of isolable dialkylsilylene 1 with aromatic acyl chlorides afforded aroylsilanes 3a–3c exclusively. Aroylsilanes 3a–3c were characterized by (1)H-, (13)C-, and (29)Si-NMR spectroscopy, high-resolution mass spectrometry (HRMS), and single-crystal molecular structure analysis. The reaction mechanisms are discussed in comparison with related reaction of 1 with chloroalkanes and chlorosilanes.
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spelling pubmed-62733702018-12-28 Reactions of an Isolable Dialkylsilylene with Aroyl Chlorides. A New Route to Aroylsilanes Xiao, Xu-Qiong Liu, Xupeng Lu, Qiong Li, Zhifang Lai, Guoqiao Kira, Mitsuo Molecules Article The reactions of isolable dialkylsilylene 1 with aromatic acyl chlorides afforded aroylsilanes 3a–3c exclusively. Aroylsilanes 3a–3c were characterized by (1)H-, (13)C-, and (29)Si-NMR spectroscopy, high-resolution mass spectrometry (HRMS), and single-crystal molecular structure analysis. The reaction mechanisms are discussed in comparison with related reaction of 1 with chloroalkanes and chlorosilanes. MDPI 2016-10-15 /pmc/articles/PMC6273370/ /pubmed/27754460 http://dx.doi.org/10.3390/molecules21101376 Text en © 2016 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC-BY) license (http://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Xiao, Xu-Qiong
Liu, Xupeng
Lu, Qiong
Li, Zhifang
Lai, Guoqiao
Kira, Mitsuo
Reactions of an Isolable Dialkylsilylene with Aroyl Chlorides. A New Route to Aroylsilanes
title Reactions of an Isolable Dialkylsilylene with Aroyl Chlorides. A New Route to Aroylsilanes
title_full Reactions of an Isolable Dialkylsilylene with Aroyl Chlorides. A New Route to Aroylsilanes
title_fullStr Reactions of an Isolable Dialkylsilylene with Aroyl Chlorides. A New Route to Aroylsilanes
title_full_unstemmed Reactions of an Isolable Dialkylsilylene with Aroyl Chlorides. A New Route to Aroylsilanes
title_short Reactions of an Isolable Dialkylsilylene with Aroyl Chlorides. A New Route to Aroylsilanes
title_sort reactions of an isolable dialkylsilylene with aroyl chlorides. a new route to aroylsilanes
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273370/
https://www.ncbi.nlm.nih.gov/pubmed/27754460
http://dx.doi.org/10.3390/molecules21101376
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