Temperature-Triggered Switchable Helix-Helix Inversion of Poly(phenylacetylene) Bearing l-Valine Ethyl Ester Pendants and Its Chiral Recognition Ability

A phenylacetylene containing the l-valine ethyl ester pendant (PAA-Val) was synthesized and polymerized by an organorhodium catalyst (Rh(nbd)BPh(4)) to produce the corresponding one-handed helical cis-poly(phenylacetylene) (PPAA-Val). PPAA-Val showed a unique temperature-triggered switchable helix-s...

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Detalles Bibliográficos
Autores principales: Zhou, Yanli, Zhang, Chunhong, Qiu, Yuan, Liu, Lijia, Yang, Taotao, Dong, Hongxing, Satoh, Toshifumi, Okamoto, Yoshio
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273589/
https://www.ncbi.nlm.nih.gov/pubmed/27879637
http://dx.doi.org/10.3390/molecules21111583

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273589/
https://www.ncbi.nlm.nih.gov/pubmed/27879637
http://dx.doi.org/10.3390/molecules21111583

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