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Photo Racemization and Polymerization of (R)-1,1′-Bi(2-naphthol)

(R)-1,1’-Bi(2-naphthol) ((R)-BINOL) in an acetonitrile solution lost optical activity upon irradiation with an Hg–Xe lamp. HPLC resolution of the product indicated that (R)-BINOL was racemized upon irradiation, and SEC analysis suggested that a polymeric product was formed in the course of racemizat...

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Detalles Bibliográficos
Autores principales: Zhang, Zhaoming, Wang, Yue, Nakano, Tamaki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273637/
https://www.ncbi.nlm.nih.gov/pubmed/27854333
http://dx.doi.org/10.3390/molecules21111541