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Photo Racemization and Polymerization of (R)-1,1′-Bi(2-naphthol)
(R)-1,1’-Bi(2-naphthol) ((R)-BINOL) in an acetonitrile solution lost optical activity upon irradiation with an Hg–Xe lamp. HPLC resolution of the product indicated that (R)-BINOL was racemized upon irradiation, and SEC analysis suggested that a polymeric product was formed in the course of racemizat...
Autores principales: | Zhang, Zhaoming, Wang, Yue, Nakano, Tamaki |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273637/ https://www.ncbi.nlm.nih.gov/pubmed/27854333 http://dx.doi.org/10.3390/molecules21111541 |
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