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Facile Access to Stable Silylium Ions Stabilized by N-Heterocyclic Imines
Novel silylium ions with N-heterocyclic imines were successfully synthesized. The reaction of trimethylsilyl imidazolin-2-imine Me(3)SiNIPr (NIPr = bis(2,6-diisopropylphenyl)-imidazolin-2-imino) with B(C(6)F(5))(3) leads to dimeric imino-substituted silylium ions through a methyl group abstraction o...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273809/ https://www.ncbi.nlm.nih.gov/pubmed/27589708 http://dx.doi.org/10.3390/molecules21091155 |