Reduced Reactivity of Amines against Nucleophilic Substitution via Reversible Reaction with Carbon Dioxide

The reversible reaction of carbon dioxide (CO(2)) with primary amines to form alkyl-ammonium carbamates is demonstrated in this work to reduce amine reactivity against nucleophilic substitution reactions with benzophenone and phenyl isocyanate. The reversible formation of carbamates has been recentl...

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Detalles Bibliográficos
Autores principales: Mohammed, Fiaz S., Kitchens, Christopher L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2015
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273814/
https://www.ncbi.nlm.nih.gov/pubmed/26703563
http://dx.doi.org/10.3390/molecules21010024

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273814/
https://www.ncbi.nlm.nih.gov/pubmed/26703563
http://dx.doi.org/10.3390/molecules21010024

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