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Reduced Reactivity of Amines against Nucleophilic Substitution via Reversible Reaction with Carbon Dioxide
The reversible reaction of carbon dioxide (CO(2)) with primary amines to form alkyl-ammonium carbamates is demonstrated in this work to reduce amine reactivity against nucleophilic substitution reactions with benzophenone and phenyl isocyanate. The reversible formation of carbamates has been recentl...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2015
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273814/ https://www.ncbi.nlm.nih.gov/pubmed/26703563 http://dx.doi.org/10.3390/molecules21010024 |