σ-Bond Electron Delocalization in Oligosilanes as Function of Substitution Pattern, Chain Length, and Spatial Orientation

Polysilanes are known to exhibit the interesting property of σ-bond electron delocalization. By employing optical spectroscopy (UV-vis), it is possible to judge the degree of delocalization and also differentiate parts of the molecules which are conjugated or not. The current study compares oligosil...

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Detalles Bibliográficos
Autores principales: Hlina, Johann, Stella, Filippo, Aghazadeh Meshgi, Mohammad, Marschner, Christoph, Baumgartner, Judith
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273834/
https://www.ncbi.nlm.nih.gov/pubmed/27548126
http://dx.doi.org/10.3390/molecules21081079

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273834/
https://www.ncbi.nlm.nih.gov/pubmed/27548126
http://dx.doi.org/10.3390/molecules21081079

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