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Direct Selective Oxidative Functionalization of C–H Bonds with H(2)O(2): Mn-Aminopyridine Complexes Challenge the Dominance of Non-Heme Fe Catalysts
Non-heme iron(II) complexes are widespread synthetic enzyme models, capable of conducting selective C–H oxidation with H(2)O(2) in the presence of carboxylic acid additives. In the last years, structurally similar manganese(II) complexes have been shown to catalyze C–H oxidation with similarly high...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2016
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273867/ https://www.ncbi.nlm.nih.gov/pubmed/27809257 http://dx.doi.org/10.3390/molecules21111454 |