Direct Selective Oxidative Functionalization of C–H Bonds with H(2)O(2): Mn-Aminopyridine Complexes Challenge the Dominance of Non-Heme Fe Catalysts

Non-heme iron(II) complexes are widespread synthetic enzyme models, capable of conducting selective C–H oxidation with H(2)O(2) in the presence of carboxylic acid additives. In the last years, structurally similar manganese(II) complexes have been shown to catalyze C–H oxidation with similarly high...

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Detalles Bibliográficos
Autores principales: Ottenbacher, Roman V., Talsi, Evgenii P., Bryliakov, Konstantin P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273867/
https://www.ncbi.nlm.nih.gov/pubmed/27809257
http://dx.doi.org/10.3390/molecules21111454

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