Intramolecular Chain Hydrosilylation of Alkynylphenylsilanes Using a Silyl Cation as a Chain Carrier

Diorganyl[2-(trimethylsilylethynyl)phenyl]silanes 1a–c and methyl-substituted phenylsilanes 1d and 1e were treated with a small amount of trityl tetrakis(pentafluorophenyl)borate (TPFPB) as an initiator in benzene to afford the corresponding benzosiloles (2a–e) in moderate to good yields. However, n...

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Detalles Bibliográficos
Autores principales: Arii, Hidekazu, Nakabayashi, Kenichi, Mochida, Kunio, Kawashima, Takayuki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273890/
https://www.ncbi.nlm.nih.gov/pubmed/27490522
http://dx.doi.org/10.3390/molecules21080999

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6273890/
https://www.ncbi.nlm.nih.gov/pubmed/27490522
http://dx.doi.org/10.3390/molecules21080999

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