Double Intramolecular Transacetalization of Polyhydroxy Acetals: Synthesis of Conformationally-Restricted 1,3-Dioxanes with Axially-Oriented Phenyl Moiety

The synthesis of conformationally-restricted 1,3-dioxanes with a phenyl moiety fixed in an axial orientation at the acetalic center is described. Starting with diethyl 3-hydroxyglutarate (15), benzaldehyde acetal 12a and acetophenone ketal 12b bearing a protected 1,3,5-trihydroxypentyl side chain in...

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Detalles Bibliográficos
Autores principales: Asare-Nkansah, Samuel, Wünsch, Bernhard
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6274033/
https://www.ncbi.nlm.nih.gov/pubmed/27834880
http://dx.doi.org/10.3390/molecules21111503

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6274033/
https://www.ncbi.nlm.nih.gov/pubmed/27834880
http://dx.doi.org/10.3390/molecules21111503

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