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Synthesis, Properties and Stereochemistry of 2-Halo-1,2λ(5)-oxaphosphetanes

Results of research into four-membered 2-halo-1,2λ(5)-oxaphosphetane phosphorus(V)-heterocycles are presented. The preparation of 2-halo-1,2λ(5)-oxaphosphetanes by reaction of P-haloylides with carbonyl compounds is described. The mechanism of asynchronous [2+2]-сycloaddition of ylides to aldehydes...

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Detalles Bibliográficos
Autores principales: Kolodiazhna, Anastasy O., Kolodiazhnyi, Oleg I.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6274043/
https://www.ncbi.nlm.nih.gov/pubmed/27763512
http://dx.doi.org/10.3390/molecules21101371