Porphyrin Cobalt(III) “Nitrene Radical” Reactivity; Hydrogen Atom Transfer from Ortho-YH Substituents to the Nitrene Moiety of Cobalt-Bound Aryl Nitrene Intermediates (Y = O, NH)

In the field of cobalt(II) porphyrin-catalyzed metallo-radical reactions, organic azides have emerged as successful nitrene transfer reagents. In the pursuit of employing ortho-YH substituted (Y = O, NH) aryl azides in Co(II) porphyrin-catalyzed nitrene transfer reactions, unexpected hydrogen atom t...

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Detalles Bibliográficos
Autores principales: Goswami, Monalisa, Rebreyend, Christophe, de Bruin, Bas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6274064/
https://www.ncbi.nlm.nih.gov/pubmed/26907236
http://dx.doi.org/10.3390/molecules21020242

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6274064/
https://www.ncbi.nlm.nih.gov/pubmed/26907236
http://dx.doi.org/10.3390/molecules21020242

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