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Pentacoordinate and Hexacoordinate Mn(III) Complexes of Tetradentate Schiff-Base Ligands Containing Tetracyanidoplatinate(II) Bridges and Revealing Uniaxial Magnetic Anisotropy

Crystal structures and magnetic properties of polymeric and trinuclear heterobimetallic Mn(III)···Pt(II)···Mn(III) coordination compounds, prepared from the Ba[Pt(CN)(4)] and [Mn(L4A/B)(Cl)] (1a/b) precursor complexes, are reported. The polymeric complex [{Mn(L4A)}(2){μ(4)-Pt(CN)(4)}](n) (2a), where...

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Detalles Bibliográficos
Autores principales: Nemec, Ivan, Herchel, Radovan, Trávníček, Zdeněk
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6274172/
https://www.ncbi.nlm.nih.gov/pubmed/27941609
http://dx.doi.org/10.3390/molecules21121681