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Pentacoordinate and Hexacoordinate Mn(III) Complexes of Tetradentate Schiff-Base Ligands Containing Tetracyanidoplatinate(II) Bridges and Revealing Uniaxial Magnetic Anisotropy
Crystal structures and magnetic properties of polymeric and trinuclear heterobimetallic Mn(III)···Pt(II)···Mn(III) coordination compounds, prepared from the Ba[Pt(CN)(4)] and [Mn(L4A/B)(Cl)] (1a/b) precursor complexes, are reported. The polymeric complex [{Mn(L4A)}(2){μ(4)-Pt(CN)(4)}](n) (2a), where...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
MDPI
2016
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6274172/ https://www.ncbi.nlm.nih.gov/pubmed/27941609 http://dx.doi.org/10.3390/molecules21121681 |