Synthesis and Properties of Bis-Porphyrin Molecular Tweezers: Effects of Spacer Flexibility on Binding and Supramolecular Chirogenesis

Ditopic binding of various dinitrogen compounds to three bisporphyrin molecular tweezers with spacers of varying conformational rigidity, incorporating the planar enediyne (1), the helical stiff stilbene (2), or the semi-rigid glycoluril motif fused to the porphyrins (3), are compared. Binding const...

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Detalles Bibliográficos
Autores principales: Blom, Magnus, Norrehed, Sara, Andersson, Claes-Henrik, Huang, Hao, Light, Mark E., Bergquist, Jonas, Grennberg, Helena, Gogoll, Adolf
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2015
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6274253/
https://www.ncbi.nlm.nih.gov/pubmed/26703562
http://dx.doi.org/10.3390/molecules21010016

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6274253/
https://www.ncbi.nlm.nih.gov/pubmed/26703562
http://dx.doi.org/10.3390/molecules21010016

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