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Synthesis of Thioethers by InI(3)-Catalyzed Substitution of Siloxy Group Using Thiosilanes

The substitution of a siloxy group using thiosilanes smoothly occurred in the presence of InI(3) catalyst to yield the corresponding thioethers. InI(3) was a specifically effective catalyst in this reaction system, while other typical Lewis acids such as BF(3)·OEt(2), AlCl(3), and TiCl(4) were ineff...

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Detalles Bibliográficos
Autores principales: Nishimoto, Yoshihiro, Okita, Aya, Baba, Akio, Yasuda, Makoto
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2016
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6274403/
https://www.ncbi.nlm.nih.gov/pubmed/27782065
http://dx.doi.org/10.3390/molecules21101330