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Controlled Release of Carbon Monoxide from a Pseudo Electron-Deficient Organometallic Complex
[Image: see text] A 16-electron iridium organometallic is reacted with carbon monoxide to form an 18-electron CO-adduct. This CO-adduct is stable for weeks in the solid state, but quickly reverts to its parent 16-e complex in tetrahydrofuran solution, releasing CO((g)). Using a simple methodology, w...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
American Chemical Society
2018
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6275942/ https://www.ncbi.nlm.nih.gov/pubmed/30533578 http://dx.doi.org/10.1021/acsomega.8b02154 |