Controlled Release of Carbon Monoxide from a Pseudo Electron-Deficient Organometallic Complex

[Image: see text] A 16-electron iridium organometallic is reacted with carbon monoxide to form an 18-electron CO-adduct. This CO-adduct is stable for weeks in the solid state, but quickly reverts to its parent 16-e complex in tetrahydrofuran solution, releasing CO((g)). Using a simple methodology, w...

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Autores principales: Pitto-Barry, Anaïs, Barry, Nicolas P. E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2018
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6275942/
https://www.ncbi.nlm.nih.gov/pubmed/30533578
http://dx.doi.org/10.1021/acsomega.8b02154
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author Pitto-Barry, Anaïs
Barry, Nicolas P. E.
author_facet Pitto-Barry, Anaïs
Barry, Nicolas P. E.
author_sort Pitto-Barry, Anaïs
collection PubMed
description [Image: see text] A 16-electron iridium organometallic is reacted with carbon monoxide to form an 18-electron CO-adduct. This CO-adduct is stable for weeks in the solid state, but quickly reverts to its parent 16-e complex in tetrahydrofuran solution, releasing CO((g)). Using a simple methodology, we show that this gas can subsequently be used to perform a carbonylation reaction on another molecule.
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spelling pubmed-62759422018-12-05 Controlled Release of Carbon Monoxide from a Pseudo Electron-Deficient Organometallic Complex Pitto-Barry, Anaïs Barry, Nicolas P. E. ACS Omega [Image: see text] A 16-electron iridium organometallic is reacted with carbon monoxide to form an 18-electron CO-adduct. This CO-adduct is stable for weeks in the solid state, but quickly reverts to its parent 16-e complex in tetrahydrofuran solution, releasing CO((g)). Using a simple methodology, we show that this gas can subsequently be used to perform a carbonylation reaction on another molecule. American Chemical Society 2018-11-16 /pmc/articles/PMC6275942/ /pubmed/30533578 http://dx.doi.org/10.1021/acsomega.8b02154 Text en Copyright © 2018 American Chemical Society This is an open access article published under a Creative Commons Attribution (CC-BY) License (http://pubs.acs.org/page/policy/authorchoice_ccby_termsofuse.html) , which permits unrestricted use, distribution and reproduction in any medium, provided the author and source are cited.
spellingShingle Pitto-Barry, Anaïs
Barry, Nicolas P. E.
Controlled Release of Carbon Monoxide from a Pseudo Electron-Deficient Organometallic Complex
title Controlled Release of Carbon Monoxide from a Pseudo Electron-Deficient Organometallic Complex
title_full Controlled Release of Carbon Monoxide from a Pseudo Electron-Deficient Organometallic Complex
title_fullStr Controlled Release of Carbon Monoxide from a Pseudo Electron-Deficient Organometallic Complex
title_full_unstemmed Controlled Release of Carbon Monoxide from a Pseudo Electron-Deficient Organometallic Complex
title_short Controlled Release of Carbon Monoxide from a Pseudo Electron-Deficient Organometallic Complex
title_sort controlled release of carbon monoxide from a pseudo electron-deficient organometallic complex
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6275942/
https://www.ncbi.nlm.nih.gov/pubmed/30533578
http://dx.doi.org/10.1021/acsomega.8b02154
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