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Single-Electron Redox Chemistry on the [Cp*Rh] Platform Enabled by a Nitrated Bipyridyl Ligand

[Cp*Rh] complexes (Cp* = pentamethylcyclopentadienyl) are attracting renewed interest in coordination chemistry and catalysis, but these useful compounds often undergo net two-electron redox cycling that precludes observation of individual one-electron reduction events. Here, we show that a [Cp*Rh]...

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Detalles Bibliográficos
Autores principales: Moore, William N. G., Henke, Wade C., Lionetti, Davide, Day, Victor W., Blakemore, James D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6278249/
https://www.ncbi.nlm.nih.gov/pubmed/30400193
http://dx.doi.org/10.3390/molecules23112857