Investigation of nitro–nitrito photoisomerization: crystal structure of trans-chlorido­nitro­(1,4,8,11-tetra­aza­cyclo­tetra­decane-κ(4) N,N′,N′′,N′′′)cobalt(III) chloride

The reaction cavity of the nitro group in the crystal of the title compound, [CoCl(NO(2))(C(10)H(24)N(4))]Cl, (I), was investigated to confirm that it offers sufficient free space for linkage isomerization to occur in accordance with the observed photochemical reactivity. The complex cation has crys...

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Detalles Bibliográficos
Autores principales: Ohba, Shigeru, Tsuchimoto, Masanobu, Yamada, Naoki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2018
Materias:
Research Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6281089/
https://www.ncbi.nlm.nih.gov/pubmed/30574399
http://dx.doi.org/10.1107/S205698901801678X

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6281089/
https://www.ncbi.nlm.nih.gov/pubmed/30574399
http://dx.doi.org/10.1107/S205698901801678X

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