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Investigation of nitro–nitrito photoisomerization: crystal structure of trans-chloridonitro(1,4,8,11-tetraazacyclotetradecane-κ(4) N,N′,N′′,N′′′)cobalt(III) chloride

The reaction cavity of the nitro group in the crystal of the title compound, [CoCl(NO(2))(C(10)H(24)N(4))]Cl, (I), was investigated to confirm that it offers sufficient free space for linkage isomerization to occur in accordance with the observed photochemical reactivity. The complex cation has crys...

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Detalles Bibliográficos
Autores principales:	Ohba, Shigeru, Tsuchimoto, Masanobu, Yamada, Naoki
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	International Union of Crystallography 2018
Materias:	Research Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6281089/ https://www.ncbi.nlm.nih.gov/pubmed/30574399 http://dx.doi.org/10.1107/S205698901801678X

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