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Organocatalyzed ring-opening copolymerization of α-bromo-γ-butyrolactone with ε-caprolactone for the synthesis of functional aliphatic polyesters – pre-polymers for graft copolymerization

Diphenyl phosphate (DPP) was exploited as an organocatalyst to synthesize copolymers by ring-opening polymerization with α-bromo-γ-butyrolactone (αBrγBL) and ε-caprolactone (εCL) as monomers and polyethylene glycol (PEG) as initiator. The conversion rates of monomers and molecular weights of copolym...

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Detalles Bibliográficos
Autores principales: Gao, Chen, Tsou, Chi-Hui, Zeng, Chun-Yan, Yuan, Li, Peng, Rui, Zhang, Xue-Mei
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Taylor & Francis 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6282472/
https://www.ncbi.nlm.nih.gov/pubmed/30532666
http://dx.doi.org/10.1080/15685551.2018.1550288