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Switching Chemoselectivity: Using Mechanochemistry to Alter Reaction Kinetics
A reaction manifold has been discovered in which the chemoselectivity can be altered by switching between neat milling and liquid assisted grinding (LAG) with polar additives. After investigation of the reaction mechanism, it has been established that this switching in reaction pathway is due to the...
| Autores principales: | , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6282732/ https://www.ncbi.nlm.nih.gov/pubmed/30335216 http://dx.doi.org/10.1002/anie.201810141 |