Base-induced reversible H(2) addition to a single Sn(ii) centre

A range of amines catalyse the oxidative addition (OA) of H(2) to [(Me(3)Si)(2)CH](2)Sn (1), forming [(Me(3)Si)(2)CH](2)SnH(2) (2). Experimental and computational studies point to ‘frustrated Lewis pair’ mechanisms in which 1 acts as a Lewis acid and involve unusual late transition states; this is s...

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Detalles Bibliográficos
Autores principales: Turnell-Ritson, Roland C., Sapsford, Joshua S., Cooper, Robert T., Lee, Stella S., Földes, Tamás, Hunt, Patricia A., Pápai, Imre, Ashley, Andrew E.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2018
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6289099/
https://www.ncbi.nlm.nih.gov/pubmed/30627391
http://dx.doi.org/10.1039/c8sc03110j

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6289099/
https://www.ncbi.nlm.nih.gov/pubmed/30627391
http://dx.doi.org/10.1039/c8sc03110j

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