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Base-induced reversible H(2) addition to a single Sn(ii) centre
A range of amines catalyse the oxidative addition (OA) of H(2) to [(Me(3)Si)(2)CH](2)Sn (1), forming [(Me(3)Si)(2)CH](2)SnH(2) (2). Experimental and computational studies point to ‘frustrated Lewis pair’ mechanisms in which 1 acts as a Lewis acid and involve unusual late transition states; this is s...
| Autores principales: | , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2018
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6289099/ https://www.ncbi.nlm.nih.gov/pubmed/30627391 http://dx.doi.org/10.1039/c8sc03110j |