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[Rh(L-alaninate)(1,5-Cyclooctadiene)] Catalyzed Helix-Sense-Selective Polymerizations of Achiral Phenylacetylenes

The [Rh(L-alaninate)(cod)] (cod = 1,5-Cyclooctadiene) complex was synthesized and characterized. Asymmetric polymerizations of achiral phenylacetylene with two hydroxyl groups and a dodecyl group (DoDHPA) were performed by using the rhodium complex as the catalyst to provide polymers with a higher m...

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Detalles Bibliográficos
Autores principales: Wang, Qingyu, Jia, Hongge, Shi, Yongqiang, Ma, Liqun, Yang, Guoxing, Wang, Yazhen, Xu, Shuangping, Wang, Jianjun, Zang, Yu, Aoki, Toshiki
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6290612/
https://www.ncbi.nlm.nih.gov/pubmed/30961148
http://dx.doi.org/10.3390/polym10111223