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Lithium hexamethyldisilazide initiated superfast ring opening polymerization of alpha-amino acid N-carboxyanhydrides

Polypeptides have broad applications and can be prepared via ring-opening polymerization of α-amino acid N-carboxyanhydrides (NCAs). Conventional initiators, such as primary amines, give slow NCA polymerization, which requires multiple days to reach completion and can result in substantial side reac...

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Detalles Bibliográficos
Autores principales: Wu, Yueming, Zhang, Danfeng, Ma, Pengcheng, Zhou, Ruiyi, Hua, Lei, Liu, Runhui
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6294000/
https://www.ncbi.nlm.nih.gov/pubmed/30546065
http://dx.doi.org/10.1038/s41467-018-07711-y