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Lithium hexamethyldisilazide initiated superfast ring opening polymerization of alpha-amino acid N-carboxyanhydrides
Polypeptides have broad applications and can be prepared via ring-opening polymerization of α-amino acid N-carboxyanhydrides (NCAs). Conventional initiators, such as primary amines, give slow NCA polymerization, which requires multiple days to reach completion and can result in substantial side reac...
Autores principales: | Wu, Yueming, Zhang, Danfeng, Ma, Pengcheng, Zhou, Ruiyi, Hua, Lei, Liu, Runhui |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2018
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6294000/ https://www.ncbi.nlm.nih.gov/pubmed/30546065 http://dx.doi.org/10.1038/s41467-018-07711-y |
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