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Enhanced Reactivity of Aluminum Complexes Containing P-Bridged Biphenolate Ligands in Ring-Opening Polymerization Catalysis

Aluminum complexes containing [RP(O)(2-O-3,5-tBu(2)C(6)H(2))(2)](2−) [R = tBu (3a), Ph (3b)] have been synthesized, structurally characterized, and their reactivity studied in comparison with those of their [RP(2-O-3,5-tBu(2)C(6)H(2))(2)](2−) [R = tBu (2a), Ph (2b)] analogs. Treating AlMe(3) with on...

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Detalles Bibliográficos
Autores principales: Zou, Xue-Ru, Chang, Yu-Ning, Huang, Kuo-Wei, Liang, Lan-Chang
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2018
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6300491/
https://www.ncbi.nlm.nih.gov/pubmed/30619816
http://dx.doi.org/10.3389/fchem.2018.00607